Biofunctional Synthetic Chemistry Laboratory

田中生体機能合成化学研究室 • 理化学研究所

Papers:

  1. K. Tanaka, T. Goi, K. Fukase, Highly Efficient Sialylation towards α(2-3) and α(2-6)-Neu5Ac-Gal Synthesis: Significant “Fixed Dipole Effect” of N-Phthalyl Group on α-Selectivity, Synlett, 2958-2962 (2005).

  2. S. Tanaka, M. Takashina, H. Tokimoto, Y. Fujimoto, K. Tanaka, K. Fukase, Highly β-Selective Mannosylation Towards Manβ1-4GlcNAc Synthesis: TMSB(C6F5)4 as a Lewis acid/Cation-Trap Catalyst, Synlett, 2325-2328 (2005).

  3. K. Fukase, M. Takashina, Y. Hori, D. Tanaka, K. Tanaka, S. Kusumoto, Oligosaccharide Synthesis by Using Affinity Separation Based on Molecular Recognition between Podand Ether and Ammonium Ion, Synlett, 2342-2346 (2005).

  4. E. Giorgio, M. Roje, K. Tanaka, Z. Hamersak, V. Sunjic, K. Nakanishi, C. Risini, N. Berova, Determination of the Absolute Configuration of Flexible Molecules by ab initio ORD Calculations: A Case Study with Cytoxazones and Isocytoxazones, J. Org. Chem., 70, 6557-6563 (2005).

  5. E. Giorgio, K. Tanaka, W. Ding, G. Krishnamurthy, K. Pitts, G. A. Ellestad, C. Rosini, N. Berova, Theoretical Simulation of the Electronic Circular Dichroism Spectrum of Calicheamicin, Bioorg. Med. Chem., 13, 5072-5079 (2005).

  6. K. Tanaka, M. Pimentel, N. Berova, K. Nakanishi, Unique Reactivity of α-Alkoxy Ginkgolide Lactones to Nucleophilic Reagents: Preparation of New Lactol Derivatives, Bull. Chem. Soc. Jpn., 78, 1843-1850 (2005).

  7. K. Tanaka, Y. Itagaki, M. Satake, H. Naoki, T. Yasumoto, K. Nakanishi, N. Berova, Three Challenges towards the Assignment of Absolute Configuration of Gymnocin-B, J. Am. Chem. Soc., 127, 9561-9570 (2005).

  8. K. Tanaka, D. K. Kester, K. Nakanishi, N. Berova, Preparation of Ginkgolide and F-Seco-ginkgolide Lactols: The Unique Reactivity of α-Hydroxy Lactones towards NaBH4, Tetrahedron Lett., 46, 531-534 (2005).

  9. K. Tanaka, G. Pescitelli, K. Nakanishi, N. Berova, Fluorescence Detected Exciton Coupled Circular Dichroism: Development of New Fluorescent Reporter Groups for Structural Studies, Monatsh. Chem., 136, 367-395 (2005).

  10. T. Nehira, K. Tanaka, T. Takakuwa, C. Ohshima, H. Masago, G. Pescitelli, A. Wada, N. Berova, Development of a Universal Ellipsoidal Mirror Device for Fluorescence Detected Circular Dichroism (FDCD) - Elimination of Polarization Artifacts, Appl. Spectrosc., 59, 121-125 (2005).


Personal Accounts:

  1. 田中克典, 勝村成雄, 酵素阻害機構に学ぶ速やかな6π-アザ電子環状反応とその展開, 有機合成化学協会誌, 63, 696-708 (2005).