業績リスト (2016/02)

学術論文（査読あり）

  1. Shota Yamazaki, Masahiko Harata, Yuya Ueno, Masaaki Tsubouchi, Keiji Konagaya, Yuichi Ogawa, Goro Isoyama, Chiko Otani and Hiromichi Hoshina “Propagation of THz irradiation energy through aqueous layers: Demolition of actin filaments in living cells.” Scientific Reports, 10, 9008 (2020)
  2. Hiromichi Hoshina, Yuichi Saito, Takumi Furuhashi, Tomomi Shimazaki, Manabu Sawada, Yasunori Hioki, Chiko Otani “Terahertz Spectroscopy for Characterization of Hydrogen Bonding and Cross-linked Structure Dynamics in Polyurethane” Journal of Infrared, Millimeter, and Terahertz Waves 41, pp.265-275 (2020)
  3. Hiromichi Hoshina, Takuro Kanemura and Michael T. Ruggiero “Exploring the Dynamics of Bound Water in Nylon Polymers with Terahertz Spectroscopy” Journal of Physical Chemistry B 124, pp.422-429 (2020)
  4. Dian Marlina, Yeonju Park, Hiromichi Hoshina, Yukihiro Ozaki, Young Mee Jung and Harumi Sato “A study on blend ratio-dependent far-IR and low-frequency Raman spectra and WAXD patterns of poly(3-hydroxybutyrate)/poly(4-vinylphenol) using homospectral and heterospectral two-dimensional correlation spectroscopy” Analytical Sciences 36 pp.731-737 (2020)
  5. Shigeki Yamamoto, Erika Ohnishi, Harumi Sato, Hiromichi Hoshina, Daitaro Ishikawa and Yukihiro Ozaki “Low-Frequency Vibrational Modes of Nylon 6 Studied by Using Infrared and Raman Spectroscopies and Density Functional Theory Calculations” Journal of Physical Chemistry B, vol. 123 pp.5368-5376 (2019)
  6. Dian Marlina, Hiromichi Hoshina, Yukihiro Ozaki, Harumi Sato “Crystallization and crystalline dynamics of poly(3-hydroxybutyrate) / poly(4-vinylphenol) polymer blends studied by low-frequency vibrational spectroscopy” Polymer, 181, 121790 (2019)
  7. Fumita Nishimura, Hiromichi Hoshina, Yukihiro Ozaki, Harumi Sato “Isothermal crystallization of poly(glycolic acid) studied by terahertz and infrared spectroscopy and SAXS/WAXD simultaneous measurements” Polymer Journal, 51, 237-245 (2019)
  8. S. Yamazaki, M. Harata, T. Idehara, K. Konagaya, G. Yokoyama, H. Hoshina, Y. Ogawa “Actin polymerization is activated by terahertz irradiation” Sci. Rep. 8, 9990 (2018)
  9. H. Hoshina, Y. Iwasaki, E. Katahira, M. Okamoto, C. Otani “Structure and dynamics of bound water in poly (ethylene-vinylalcohol) copolymers studied by terahertz spectroscopy” Polymer, 148, pp. 49–60 (2018)
  10. 3. Chihiro Funaki, Shigeki Yamamoto, Hiromichi Hoshina, Yukihiro Ozaki, Harumi Sato “Three different kinds of weak C-H/O=C inter- and intramolecular interactions in poly(ε-caprolactone) studied by using terahertz spectroscopy, infrared spectroscopy and quantum chemical calculations” Polymer, 137, pp.245-254 (2018)
  11. Dian Marlina, Harumi Sato, Hiromichi Hoshina, Yukihiro Ozaki “Intermolecular interactions of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (P(HB-co-HV)) with PHB-type crystal structure and PHV-type crystal structure studied by low-frequency Raman and terahertz spectroscopies” Polymer, 135, pp.331-337 (2017)
  12. Shigeki Yamamoto, Mai Miyada, Harumi Sato, Hiromichi Hoshina, Yukihiro Ozaki “Low-Frequency Vibrational Modes of Poly(glycolic acid) and Thermal Expansion of Crystal Lattice Assigned Based on DFT-Spectral Simulation Aided with a Fragment Method” The Journal of Physical Chemistry Part B, 121, pp.1128-1138 (2017)
  13. Chihiro Funaki, Takuya Toyouchi, Hiromichi Hoshina, Yukihiro Ozaki, Harumi Sato “Terahertz imaging of the distribution of crystallinity and crystalline orientation in a poly (ε-caprolactone) film” Applied Spectroscopy, accepted (2017)
  14. Hiromichi Hoshina, Russell Sliter, Aakash Ravi, Susumu Kuma, Takamasa Momose, Andrey Vilesov “Ro-vibrational spectra of (para-H2)N-CH4 in He droplets” ChemPhysChem, 17(22),3818-3825 (2016)
  15. Hiromichi Hoshina, Hal Suzuki, Chiko Otani, Masaya Nagai, Keigo Kawase, Akinori Irizawa, Goro Isoyama “Polymer Morphological Change Induced by Terahertz Irradiation” Scientific Reports, 6, 27180 (2016)
  16. Takeshi Matsukawa, Hiromichi Hoshina, Akinori Hoshikawa, Chiko Otani, Toru Ishigaki “Temperature Dependence of Crystal Structure and THz Absorption Spectra of Organic Nonlinear Optical Stilbazolium Material for High-Output THz-Wave Generation” Journal of Infrared, Millimeter, and Terahertz Waves 37, pp.540-550 (2016)
  17. Hiromichi Hoshina, Mikhail N. Slipchenko, Kirill Prozument, Deepak Verma, Michael W. Schmidt, Joseph Ivanic, and Andrey F. Vilesov “Infrared Spectroscopy and Structure of (NO)n Clusters” The Journal of Physical Chemistry A, 120 (4), pp. 527–534 (2016)
  18. Mikhail N. Slipchenko, Hiromichi Hoshina, Daniil Y Stolyarov, Boris Sartakov, and Andrey F. Vilesov “Internal Rotation of Methane Molecules in Large Clusters” J. Phys. Chem. Lett 7 (1), pp.47–50 (2016)
  19. Hai-Wei Du, Hiromichi Hoshina, Chiko Otani, and Katsumi Midorikawa “Terahertz waves radiated from two noncollinear femtosecond plasma filaments” Applied Physics Letters 107, 211113 (2015)
  20. Hiromichi Hoshina, Dmitri Skvortsov, Mikhail N. Slipchenko, Boris G. Sartakov, and Andrey F. Vilesov “Rotation of methane molecules in dimers and small clusters” The Journal of Chemical Physics 143, 084305 (2015)
  21. Hal Suzuki, Shinya Ishii, Chiko Otani, Hiromichi Hoshina “Low-frequency vibrations of polyamide-6 as a function of temperature and thermal history investigated by terahertz absorption spectroscopy” European Polymer Journal 67, pp.284–291 (2015)
  22. Hal Suzuki, Hiromichi Hoshina, Chiko Otani “Kinetics of Polymorphic Transitions of Cyclohexanol Investigated by Terahertz Absorption Spectroscopy” Crystal Growth & Design, 14, pp.4087-4093 (2014)
  23. Hiromichi Hoshina, Atsumi Ozaki, Yusuke Itagaki, Setsuko Yajima, Hal Suzuki, Shinya Ishii, Misaki Ishida, Tetsuji Uchiyama, Keiichi Kimura, and Chiko Otani “Sol–Gel Transition of Organogels Observed by Terahertz Spectroscopy” Chem. Phys. Lett., 608, pp. 173–176 (2014)
  24. Hiromichi Hoshina, Shinya Ishii and Chiko Otani “Separation of overlapping vibrational peaks in terahertz spectra using two-dimensional correlation spectroscopy” J. Mol. Structure, 1069, pp.152-156 (2014)
  25. Luis F. Gomez, Russell Sliter, Dmitry Skvortsov, Hiromichi Hoshina, Gary E.　Douberly, and Andrey F. Vilesov　“Infrared Spectra in the 3 μm Region of Ethane and Ethane Clusters in Helium Droplets”　J. Phys. Chem. A, 117 (50), pp. 13648-13653 (2013)
  26. Hal Suzuki, Shinya Ishii, Harumi Sato, Shigeki Yamamoto, Yusuke Morisawa, Yukihiro Ozaki, Tetsuji Uchiyama, Chiko Otani, Hiromichi Hoshina　"Brill transition of nylon-6 characterized by low-frequency vibration through terahertz absorption spectroscopy”　Chemical Physics Letters, 575, pp. 36–39 (2013)
  27. Hiromichi Hoshina, Shinya Ishii, Shigeki Yamamoto, Yusuke Morisawa, Harumi Sato, Tetsuji Uchiyama, Yukihiro Ozaki, Chiko Otani　“Terahertz Spectroscopy in Polymer Research: Assignment of Intermolecular Vibrational Modes and Structural Characterization of Poly(3-Hydroxybutyrate)”　IEEE Transactions on Terahertz Science and Technology, 3(3), pp. 248-258 (2013) (invited paper)
  28. Shigeki Yamamoto, Yusuke Morisawa, Harumi Sato, Hiromichi Hoshina, and Yukihiro Ozaki　"Quantum Mechanical Interpretation of Intermolecular Vibrational Modes of Crystalline Poly‑(R)‑3-Hydroxybutyrate Observed in Low-Frequency Raman and Terahertz Spectra"　The Journal of Physical Chemistry B, 117, pp.2180-2187 (2013)
  29. H. Naito, Y. Ogawa, H. Hoshina, S. Sultana and N. Kondo　“Analysis of Intermolecular Interaction of Poly(N-isopropylacrylamide) Solution with Attenuated Total Reflectance Terahertz Spectroscopy” Applied Physics Letters, 100, pp.191102-1-3 (2012)
  30. Hiromichi Hoshina, Shinya Ishii, Yusuke Morisawa, Harumi Sato, Yukihiro Ozaki, and Chiko Otani "Isothermal Crystallization of Poly(3-hydroxybutyrate) Studied by Terahertz Two-dimensional Correlation Spectroscopy" Applied Physics Letters, 100, pp.011907-1-3 (2012)
  31. Hiromichi Hoshina, Mizuho Fushitani, and Takamasa Momose　“Infrared spectroscopy of rovibrational transition of methyl radicals (CH3, CD3) in solid parahydrogen”　Journal of Molecular Spectroscopy, 268, pp.164-172 (2011)
  32. Hiromichi Hoshina, Yusuke Morisawa, Harumi Sato, Hiroaki Minamide, Isao Noda, Yukihiro Ozaki, and Chiko Otani "Polarization and temperature dependent spectra of poly(3-hydroxyalkanoate)s measured at terahertz frequencies" Physical Chemistry Chemical Physics, 13 (20), pp.9173-9179 (2011)
  33. K. Kawase, H. Hoshina, A. Iwasaki, Y. Sasaki and T. Shibuya "Mail screening applications of terahertz radiation," Electronics Letters, 46, pp. S66-S68 (2010).
  34. Hiromichi Hoshina, Yusuke Morisawa , Harumi Sato , Akitsugu Kamiya , Isao Noda , Yukihiro Ozaki , Chiko Otani　“Higher order conformation of poly(3-hydroxyalkanoate)s studied by terahertz time-domain spectroscopy” Applied Physics Letters, 96, pp.101904-1-3 (2010)
  35. Hiromichi Hoshina, Dmitry Skvortsov , Boris Sartakov and Andrey Vilesov “Rotation of methane and silane molecules in He droplets” The Journal of Chemical Physics, 132, pp.074302-1-8 (2010)
  36. Hideo Sagawa, Jana Mendrok, Takamasa Seta, Hiromichi Hoshina, Philippe Baron, Kodai Suzuki, Iwao Hosako, Chiko Otani, Paul Hartogh, Yasuko Kasai “Pressure broadening coefficients of H2O induced by CO2 for Venus atmosphere” Journal of Quantitative Spectroscopy & Radiative Transfer, 110, pp.2027-2036 (2009)
  37. Hiromichi Hoshina, Aya Hayashi, Norio Miyoshi, Fumiaki Miyamaru and Chiko Otani “Terahertz pulsed imaging of frozen biological tissues” Applied Physics Letters, 94, pp.123901-1-3 (2009)
  38. Hiromichi Hoshina, Yoshiaki Sasaki, Aya Hayashi, Chiko Otani and Kodo Kawase “Noninvasive Mail Inspection System with Terahertz Radiation”　Applied Spectroscopy, 63(1), pp.81-86 (2009)
  39. Hiromichi Hoshina, Takamasa Seta, Toshiyuki Iwamoto, Yasuko Kasai, Iwao Hosako, and Chiko Otani　“Measurement of Precise Pressure Broadening Parameters of Water Vapor with a Terahertz Time Domain Spectrometer” Journal of Quantitative Spectroscopy and Radiative Transfer 109, pp.2303-2314 (2008)
  40. Takamasa Seta, Hiromichi Hoshina, Yasuko Kasai, Iwao Hosako, Chiko Otani,　Stefan Lossow, Joachim Urban, Mattias Ekström, Patric Eriksson, and Donal Murtagh “Pressure broadening coefficients of the water vapor lines at 556.936 and 752.033 GHz” Journal of Quantitative Spectroscopy and Radiative Transfer, 109, pp.144-150 (2008)
  41. 保科宏道 「ケモメトリクスを用いたテラヘルツ分光イメージデータ解析と肝癌組織への適用」 分光研究 56(5) pp.207-213 (2007)
  42. S. Nakajima, H. Hoshina, M. Yamashita, C. Otani, N. Miyoshi　“Terahertz imaging diagnostics of the cancer tissues with Chemometrics technique”　Applied Physics Letters, 90, 041102-1-3 (2007)
  43. Mizuho Fushitani, Yuki Miyamoto, Hiromichi Hoshina, and Takamasa Momose "In Situ Photolysis of CD3I in Solid Orthodeuterium" The Journal of Physical Chemistry A, 111, pp.12629-12634 (2007)
  44. Y. Morisawa, M. Fushitani, Y. Kato, H. Hoshina, Z. Simizu, S. Watanabe, Y. Miyamoto, Y. Kasai, K. Kawaguchi, and T. Momose “Correlation between Nuclear Spin Ratio of Cyclic C3H2 and Chemical Evolution in TMC-1 Cores” The Astrophysical Journal, 642, pp.954–965 (2006)
  45. H. Hoshina, J. Lucrezi, M. N. Slipchenko, K. E. Kuyanov, A. F. Vilesov “Satellite Band in the Rovibrational Spectrum of CO2 in Helium Droplets” Physical Review Letters, 94, pp.195301-1-4 (2005).
  46. T. Momose, M. Fushitani, H. Hoshina “Chemical reactions in quantum crystals” International Reviews in Physical Chemistry, 24, pp.533-552 (2005)
  47. Y. Morisawa, H. Hoshina, Y. Kato, Z. Simizu, S. Kuma, N. Sogoshi, M. Fushitani, S. Watanabe, Y. Miyamoto, T. Momose, Y. Kasai and K. Kawaguchi “Search CCH-, NCO-, and NCS- Negative Ions in Molecular Clouds” Publication of the Astronomical Society of Japan, 57, pp.325-334 (2005)
  48. H. Hoshina, Y. Kato, Y. Morisawa, T. Wakabayashi and T. Momose “UV and IR absorption spectra of C3 embedded in solid para-hydrogen” Chemical Physics, 300, pp.69-77 (2004)
  49. H. Hoshina, M. Fushitani, T. Momose and T. Shida “Tunneling chemical reactions in solid parahydrogen: Direct measurement of the rate constants of R+H2 ->RH+H (R=CD3,CD2H,CDH2,CH3) at 5K” The Journal of Chemical Physics, 120, pp.3706-3715 (2004)
  50. T. Momose, H. Hoshina, M. Fushitani and H. Katsuki, “High-resolution spectroscopy and the analysis of ro-vibrational transitions of molecules in solid parahydrogen” Vibrational Spectroscopy, 34, pp.95-108 (2004)
  51. S. Tam, M. E. Fajardo, H. Katsuki, H. Hoshina, T. Wakabayashi and T. Momose “High resolution infrared absorption spectra of methane molecules isolated in solid parahydrogen matrices” The Journal of Chemical Physics, 111, pp.4191-4198 (1999)
  52. H. Hoshina, T. Wakabayashi, T. Momose and T. Shida, “Infrared spectroscopic study of rovibrational of perdeuterated methane (CD4) trapped in parahydrogen crystal” The Journal of Chemical Physics, 110, pp.5728-5733 (1999)
  53. T. Momose, H. Hoshina, N. Sogoshi, H. Katsuki, T. Wakabayashi and T. Shida “Tunneling chemical reactions in solid parahydrogen: a case of CD3 + H2 -> CD3H + H at 5K” The Journal of Chemical Physics, 108, pp.7334-7338 (1998)
  54. T. Momose, H. Katsuki, H. Hoshina, N. Sogoshi, T. Wakabayashi and T. Shida “High Resolution Laser Spectroscopy of Methane Clusters Trapped in Solid Parahydrogen.” The Journal of Chemical Physics, 107, pp.7717-7720 (1997)

総説

  1. 保科宏道，鈴木晴，山本茂樹，矢嶋摂子 「テラヘルツ振動分光から見えるソフトマテリアルの構造と水素結合」　応用物理 84号 pp.525-529 (2015)
  2. 保科宏道，林朱，大谷知行，上野茂明，小川雄一　「テラヘルツイメージング・分光による凍結食品計測の可能性」　冷凍 90 419-426 (2015)
  3. 森澤勇介，保科宏道，尾崎幸洋 「広がる振動分光法の世界 -超短パルス光源がもたらした進歩-」 光学　40巻8号　pp.388-401 (2011)



著書

  1. 「テラヘルツ技術総覧」　９．２．２章「分光」　エヌジーティー　2007年

外部資金

  1. 平成１９年度　がん研究助成金　（がん研究振興財団）　研究代表者
    「テラヘルツ波による凍結癌組織のイメージング診断手法の開発」
  2. 平成１９－２１年度　科研費補助金　基盤研究（B）　連携研究者
    「テラヘルツヘテロダイン干渉計を用いた透過型・反射型イメージングシステムの開発」
  3. 平成２０－２１年度　科研費補助金　若手研究（B）　研究代表者
    「テラヘルツ二次元相関分光法の新規開発」
  4. 平成２２―２４年度　科研費補助金　基盤研究（B）　研究代表者
    「テラヘルツ－赤外二次元相関分光の開発と高分子集合体の機能発現の解明」
  5. 平成２３－２５年度　JST　産学共創基礎基盤研究　研究代表者
    「テラヘルツ分光による高分子構造の解明と操作」
  6. 平成２６－２９年度　科研費補助金　基盤研究（A）　研究代表者
    「テラヘルツ・ラマン円偏光二色性分光による高分子キラル高次構造の解明と対掌性の操作」
  7. 平成２６－２８年度JST　産学共創基礎基盤研究　研究分担者
    「テラヘルツイメージング分光による高分子材料の劣化の可視化と深さ方向分析 」　

特許

  1. 大谷知行、林伸一郎、宮丸文章、保科宏道、小川雄一、阿部 香織
    「エタノール混合ガソリンの成分分析装置および方法」
    特願 2007-319492（出願日：平成19年12月11日）

学位論文

修士学位論文
固体パラ水素中に補足した分子の分光学的研究　
（２０００年１月　京都大学）
博士学位論文
Spectroscopy and dynamics of small molecules in solid parahydrogen
（２００３年７月　京都大学）


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