研究業績Publications
2019年 |
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In Situ Generation of Silyl Anion Species with Si–B Bond Activation Allowing Concerted Nucleophilic Aromatic Substitution of Fluoroarenes |
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Hemisquaramide Tweezers as Organocatalysts: Synthesis of Cyclic Carbonates from Epoxides and CO2 |
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A New Route to the Efficient Metalation of Unfunctionalized Aromatics |
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A Protocol for an Iodine–Metal Exchange Reaction on Cubane Using Lithium Organozincates |
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Characterization of A Small Molecule that Promotes Cell Cycle Activation of Human Induced Pluripotent Stem Cell-derived Cardiomyocytes |
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A Solvent-free and Vacuum-free Melt-processing Method to Fabricate Highly Crystalline Organic Semiconducting Layers for Organic Electronic Applications |
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BOOK & REVIEW |
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Recent Advances in the Synthetic Chemistry of Bicyclo[1.1.1]pentane |
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理論計算による生合成経路の探索 ー生合成リデザインへの挑戦ー |
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2018年 |
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Cross-coupling polycondensation via C–O or C–N bond cleavage |
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Stable Thiele’s Hydrocarbon Derivatives Exhibiting Near-Infrared Absorption/Emission and Two-Step Electrochromism. |
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Structural and Computational Bases for Dramatic Skeletal Rearrangement in Anditomin Biosynthesisy. |
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Development of a Series of Practical Fluorescent Chemical Tools To Measure pH Values in Living Samples |
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N-Alkynylpyridinium Salts: Highly Electrophilic Alkyne-Pyridine Conjugates as Precursors of Cationic Nitrogen-Embedded Polycyclic Aromatic Hydrocarbons |
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Computational Studies on Biosynthetic Carbocation Rearrangements leading to Quiannulatene: Initial Conformation Regulates Biosynthetic Route, Stereochemistry, and Type of Skeleton |
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Control of the Stereochemical Course of [4+2] Cycloaddition during trans-Decalin Formation by Fsa2-Family Enzymes |
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In Situ Generation of Silylzinc by Si–B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes |
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From Aniline to Aryl Ether: A Facile, Efficient and Versatile Synthetic Protocol Employing Mild Conditions |
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"Dumbbell"- and "Clackers"-Shaped Dimeric Derivatives of Monocarba-closo-dodecaborate |
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Discovery of a small molecule to increase cardiomyocytes and protect the heart after ischemic injury. |
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Theoretical Study of Sesterfisherol Biosynthesis: Computational Prediction of Key Amino Acid Residue in Terpene Synthase |
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Direct Synthesis of Aryl-annulated [c]Carbazoles by Gold(I)-catalysed Cascade Reaction of Azide-diynes and Arenes |
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Near-Infrared Fluorescence from In-Plane-Aromatic Cycloparaphenylene Dications. |
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Computational Study on a Puzzle in the Biosynthetic Pathway of Anthocyanin: Why is an Enzymatic Oxidation/ Reduction Process Required for a Simple Tautomerization? |
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Safer Synthesis of (Diacetoxyiodo)arenes using Sodium Hypochlorite Pentahydrate (NaClO•5H2O) |
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Mechanistic Study on Aryl Exchange Reaction of Diaryl-λ3-iodane with Aryl Iodide |
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Deprotonative Metalation of Methoxy-Substituted Arenes Using Lithium 2,2,6,6-Tetramethylpiperidide: Experimental and Computational Study |
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One-pot Annulation for Biaryl-fused Monocarba-closo-dodecaborate via Aromatic B–H Bond Disconnection |
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Synthesis of a chiral [2]rotaxane: Induction of a helical structure through double threading |
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Analysis of Degradation Products of Nerve Agents via Post-pentafluorobenzylation Lliquid Chromatography-tandem Mass Spectrometry |
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The Energetic Viability of ∆1-Piperideine Dimerization in Lysine-derived Alkaloid Biosynthesis |
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Influence of perfluorinated ionomer in PEDOT:PSS on the rectification and degradation of organic photovoltaic cells. |
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Simultaneous Edge-on to Face-on Reorientation and 1D Alignment of Small π-Conjugated Molecules Using Room-Temperature Mechanical Rubbing |
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Dearylation of Arylphosphine Oxides by a Sodium Hydride-Iodide Composite |
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BOOK & REVIEW |
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「三重結合のトランス選択的官能基化–擬分子内型活性化を利用した効率的ホウ素化反応–」 |
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「理論計算と実験化学による新反応・新材料・新機能開発」 |
「Lewis 塩基によるホウ素試薬の活性化を基盤とした ホウ素化反応の開発」 |
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Radical Multicomponent Carboamination of [1.1.1]Propellane |
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Transition Metal-Free trans-Selective Alkynylboration of Alkynes |
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Naked d-Orbital in a Centrochiral Ni(II) Complex as a Catalyst for Asymmetric [3+2] Cycloaddition |
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One-step Conversion of Levulinic Acid to Succinic Acid Using I2 / t-BuOK System: The Iodoform Reaction Revisited. |
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Discovery and Mechanistic Characterization of Selective Inhibitors of H2S-producing Enzyme: 3-Mercaptopyruvate Sulfurtransferase (3MST) Targeting Active-site Cysteine Persulfide |
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Nucleophilic Amination of Methoxy Arenes by a Sodium Hydride-Iodide Composite |
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Effects of N-Oxidation on Heteroaromatic Macrocycles: Synthesis, Electronic Structures, Spectral Properties, and Reactivities of Tetraazaporphyrin meso-N-Oxides |
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Organozinc-Mediated Direct C–C Bond Formation via C–N Bond Cleavage of Ammonium Salt |
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"Naked" Lithium Cation: Strongly Activated Metal Cations Facilitated by Carborane Anions |
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Focused Genome Mining of Structurally Related Sesterterpenes: Enzymatic Formation of Enantiomeric and Diastereomeric Products |
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Hitoyol A and B, Two Norsesquiterpenoids from the Basidiomycete Coprinopsis cinerea |
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Monomeric Octahedral Ruthenium(II) Complex Enabled meta C-H Nitration of Arenes with Removable Auxiliaries |
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Revisit of Organoaluminum Reagents Affords A Versatile Protocol for C–X (X = N, O, F) Bond-Cleavage Cross-Coupling: A Systematic Study |
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Quasi-Phase Diagrams at Air/Oil Interfaces and Bulk Oil Phases for Crystallization of Small-Molecular Semiconductors by Adjusting Gibbs Adsorption |
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Iodoarene-catalyzed Oxidative Transformations Using Molecular Oxygen |
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Synthesis and Photophysical Properties of Novel Benzophospholo[3,2-b]indole Derivatives |
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Water-Tunable Solvatochromic and Nanoaggregate Fluorescence: Dual Colour Visualisation and Quantification of Trace Water in Tetrahydrofuran |
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Mechanistic Insight into Ni-Catalyzed Cross-Coupling Involving Organoaluminum-Mediated C–O Bond Cleavage. A DFT Study |
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Ethereal C-O Bond Cleavage Mediated by Ni(0)-Ate Complex: A DFT Study |
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Unexpected Formation of Benziphthalocyanine Dimer: An Easily Synthesizable Dimer of Phthalocyanine Analogue |
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Catalytic Aromatic Borylation via in situ-generated Borenium Species |
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Reversibility of 3-Phenyl-2-oxindole Dimer Formation: Application to Construct Compounds with Two Distinct Vicinal All-Carbon Quaternary Centers |
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Catalyst-Dependent Intrinsic Ring-Walking Behavior on π-Face of Conjugated Polymers |
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BOOK & REVIEW |
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「原子・電子レベルで現象を理解し、分子の自在構築によって薬を科学する」 |
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「無機化合物・錯体の構造と性質」 |
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Stille Coupling via C–N Bond Cleavage |
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Direct Hydroxylation and Amination of Arenes via Deprotonative Cupration |
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Mechanistic Studies on the Generation and Properties of Super-electrophilic Singlet Carbenes from Bis(perfluoroalkanesulfonyl)bromonium Ylides |
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Fused-Fluoran Leuco Dyes with Large Color-Change Derived from Two-Step Equilibrium: iso-Aminobenzopyranoxanthenes |
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Cross-Coupling of Organolithium with Ethers or Aryl Ammonium Salts by C–O or C–N Bond Cleavage |
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Improvement in Aqueous Solubility of Retinoic Acid Receptor (RAR) Agonists by Bending the Molecular Structure |
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General Synthesis, Structure, and Optical Properties of Benzothiophene-Fused Benzoheteroles Consisting of Group 15 and 16 Elements |
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Rhodium-catalyzed (Perfluoroalkyl)olefination of Acetanilides Leading to Perfluoroalkylated Aromatics |
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Gold-Catalyzed Annulation of Alkyne Alcohols: Regioselective Construction of Functionalized 6,6- and 6,7-Bicyclic Ethers |
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Microcrystallization of a solution-processable organic semiconductor in capillaries for high performance ambipolar field-effect transistors |
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Allylic Borylation of Tertiary Allylic Alcohols: A Divergent and Straightforward Access to Allylic Boronates |
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Enhanced Organic Solar Cells Efficiency through Electronic and Eectro-optic Efects Resulting from Charge Transfers in Polymer Hole Transport Blends |
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Zinc diethyldithiocarbamate as an inducer of metallothionein in cultured vascular endothelial cells |
BOOK & REVIEW |
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Determination of Absolute Configuration of Axially Chiral 2,2'-Bipyridyl Using Vibrational Circular Dichroism (VCD) Spectra |
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Reaction Development on pai- and sigma-Conjugated Bonds and Creation of Innovative Functions |
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Development of Heteroatom Introducing Methodologies Based on Ate Complex Formation: Perfluoroalkylation, Borylation, Aromatic Hydroxylation and Amination Reactions |
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Deprotonative Metalation Using Alkali Metal-Non Alkali Metal Combination
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Development of Novel Methodologies in Organic Synthesis Based on Ate Complex Formation |
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フタロシアニン系近赤外色素の合成技術
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"Cation-Stitching Cascade": exquisite control of terpene cyclization in cyclooctatin biosynthesis |
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Conjugation between sigma- and pi-Aromaticity in 1-C-Arylated Monocarba-closo-dodecaborate Anions |
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Stannyl-Lithium: A Facile and Efficient Synthesis Facilitating Further Applications |
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Reversible Near-Infrared/Blue Mechanofluorochromism of Aminobenzopyranoxanthene |
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Aryne Polymerization Enabling Straightforward Synthesis of Elusive Poly(ortho-arylene)s |
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In-plane Aromaticity in Cycloparaphenylene Dications: A Magnetic Circular Dichroism and Theoretical Study |
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Organoaluminum-Mediated Direct Cross-Coupling Reaction |
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How and Why Does Ni(0) Promote Smooth Etheric C–O Bond Cleavage and C–C Bond Formation? A Theoretical Study |
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Perfluoroalkyl and -aryl Zinc Ate Complexes: Generation, Reactivity, and Synthetic Application |
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Dialkylzinc-mediated Cross-coupling Reaction of Perfluoroalkyl/- aryl Halides with Aryl Halides |
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Highly Chemoselective and Versatile Method for Direct Conversion of Carboxylic Acids to Ketones Utilizing Zinc Ate Complexes |
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Unexpected Metal-Free Transformation of gem-Dibromomethylene to Ketone under Acetylation Conditions |
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Why p-Cymene? Conformational Effect in Asymmetric Hydrogenation of Aromatic Ketones with a η6-Arene/Ruthenium(II) Catalyst |
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Stereoselective Synthesis and Reaction of Gold(I) (Z)-Enethiolate |
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Ambipolar organic field-effect transistors based on solution-processed single crystal microwires of a quinoidal oligothiophene derivative |
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Conformational and Optical Characteristics of Unidirectionally Twisted Binaphthyl-Bipyridyl Cyclic Dyads |
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Control of a Chiral Property of a Calix[3]aramide: The Racemization Suppressed by Intramolecular Cyclic Hydrogen Bonds and DMSO−H2O System-Induced Spontaneous Resolution |
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Direct Construction of Fused Indoles by Gold-Catalyzed Cascade Cyclization of Conjugated Diynes |
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Analysis of Chemical Equilibrium of Si-substituted Fluorescein and its Application to Red Fluorescent Probes |
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A DFT Study on the Mechanism of Nitrogen-Directed Intramolecular Aromatic Borylation: |
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Dialkylzinc-Mediated Allylic Polyfluoroarylation Reaction |
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Pd-catalyzed Cross-coupling Reaction of Lithiated Monocarba-closo-dodecaborate at the Carbon Vertex |
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Silane-Functionalized N-Heterocyclic Carbene–Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co–Si Bond |
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Synthesis and Structure of novel DinaphthoI[2,3-b;2',3'-d]- Tellurophene |
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BOOK & REVIEW |
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New Reactions, New Materials, and New Functions based on Integration of Theoretical Calculation and Synthetic Chemistry, |
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Trans-Diborylation of Alkynes: Pseudo-Intramolecular Strategy Utilizing Propargylic Alcohol Unit |
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18π Tautomeric Benziphthalocyanine: A Functional Near-IR Dye with Tunable Aromaticity |
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A two-coordinate boron cation featuring C–B(+)–C bonding |
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Non-volatile Organic Memory with Sub-millimetre Bending Radius |
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Unraveling the Electronic Structure of Azolehemiporphyrazines: Direct Spectroscopic Observation of Magnetic Dipole Allowed Nature of the Lowest π-π* Transition of 20π-Electron Porphyrinoids |
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Structural Effects in Lithiocuprate Chemistry: the Elucidation of Reactive Pentametallic Complexes |
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Synthesis and Properties of Palladium(II) Complexes of Aromatic Hemiporphyrazines |
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Helical π-Systems of Bidipyrrin-Metal Complexes |
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Binaphthyl-based Chiral Macrocyclophanes with Variously Sized Cavities: Dn-Symmetrical Structure Constructed from Unidirectionally-Inclined Rod Segments |
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Diastereoselective Deprotonative Metalation of Chiral Ferrocene Derived Acetals and Esters Using Mixed Lithium-Cadmium and Lithium-Zinc Combinations |
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Thin Reduced Graphene Oxide Interlayer with a Conjugated Block Copolymer for High Performance Non-volatile Ferroelectric Polymer Memory |
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Influence of the Grain Orientation on the Charge Transport Properties of Organic Field-Effect Transistors |
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Photophysical, Amplified Spontaneous Emission and Charge Transport Properties of Oligofluorene Derivatives in Thin Films |
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Titanium-induced Charge of Si(001) Surface Dependent on Local Configuration |
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In Situ KPFM Imaging of Local Photovoltaic Characteristics on Structured Organic Photovoltaic Devices |
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Molecular Motion Induced by Multivibronic Excitation on Semiconductor Surface |
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BOOK & REVIEW |
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The Development of C-C Cross-Coupling Reaction of Monocarba-closo-dodecaborate Anion for the Synthesis of Functional Molecules |
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Design, Synthesis, and Structure-activity Relationship Study of Organoantimony Compounds that Induce the Expression of Perlecan in Vascular Endothelial Cells |
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New Avenues in the Directed Deprotometallation of Aromatics: Recent Advances in Directed Cupration |
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New Formulas for Zincate Chemistry: Synergistic Effect and Synthetic Applications of Hetero-bimetal Ate Complexes
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Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne |
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Mechanistic Origin of Chemo- and Regioselectivity of Nickel-Catalyzed [3+2+2] Cyclization Reaction |
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Ion-Based Materials Derived from Positively and Negatively Charged Chloride Complexes of pi-Conjugated Molecules |
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Development of a New Class of Azo-based Fluorescence Probes to Detect Different Levels of Hypoxia |
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Copper-mediated C–C Cross-Coupling Reaction of Monocarba-closo-dodecaborate Anion for Construction of Functional Molecules |
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Chirality Induction by Formation of Assembled Structures Based on Anion- Responsive π-Conjugated Molecules |
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Formation and Geometrical Control of Polygon-Like Metal-Coordination Assemblies |
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Helicity Induction in Three π-conjugated Chromophores by Planar Chirality of Calixamide |
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Formation of Cyclic and Polymeric Structures from Zwitterions |
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Modified McFadyen-Stevens Reaction for a Versatile Synthesis of Aliphatic/Aromatic Aldehydes: Design, Optimization, and Mechanistic Investigations |
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Two Double Helical Modes of Bidipyrrin–Zn(II) Complexes |
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Chiroptical Control in Helical Receptor–Anion Complexes |
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Electronic Excited States in Strongly Correlated Organic Radical 1,3,5-trithia-2,4,6-triazapentalenyl (TTTA) Adsorbed on Si(001) Surface |
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A Red-Emissive Aminobenzopyrano-xanthene Dye: Elucidation of Fluorescence Emission Mechanism in Solution and Aggregate State |
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Exciton Diffusion in Near-infrared Absorbing Solution-processed Organic Thin Films |
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[closo-1-CB11H11-1-Ph]- as a Structural Element for Ionic Liquid Crystals |
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Unusual Conformational Preference of an Aromatic Secondary Urea: Solvent-dependent Open-Closed Conformational Switching of N,N'-Bis(porphyrinyl)urea |
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Synthesis of Porphyrinylamide and Observation of N-Methylation-induced trans-cis Amide Conformational Alteration |
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Direct C-C Bond Construction from Arylzinc Reagent and Aryl Halide Without an External Catalyst |
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Polycarbonates Derived from Glucose via an Organocatalytic Approach |
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Inorganic arsenic induces apoptosis through downregulation of Ube2d genes and p53 accumulation in rat proximal tubular cells |
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BOOK & REVIEW |
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Structural Analysis of Helical p-Conjugated Systems Using CD spectroscopy and Semi-empirical Molecular Orbital Calculations |
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Amidocuprates for Directed ortho Cupration (DoC): Structural Study, Mechanistic Investigation, and Chemical Requirements |
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Optical and Charge Transport Properties of an Ambipolar Quinoidal Oligothiophene Derivative |
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Organic Field-Effect Transistors Based on J-aggregate Thin Films of a Bisazomethine Dye |
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Mechanistic Understanding of Alkyne Haloboration: an Ab Initio Study |
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Bis(L-cysteinato)zincate(II) as a coordination compound that specifically induces metallothionein gene transcription without inducing cell-stress-related gene transcription |
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Electron Donor and Acceptor Spatial Distribution in Structured Bulk Heterojunction Photovoltaic Devices Induced by Periodic Photopolymerization |
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Synthesis of both enantiomers of ferrocene[1,2-c]1H-quinolin-2-one by diastereoselective deproto-zincation of sugar-derived ferrocene esters |
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Fusion of Photochromic Reaction and Synthetic Reaction: Photoassisted Cyclization to Highly Strained Chiral Azobenzenophanes |
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Chirality Induction by Ion-Pair Formation between Helical Receptor–Anion Complexes and Chiral Cations |
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Red Fluorescent Scaffold for Highly Sensitive Protease Activity Probes |
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Rectangular-Shaped Expanded Phthalocyanines with Two Central Metal Atoms |
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[18]/[20]pai Hemiporphyrazine: A Redox Switchable Near- infrared Dye |
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Aryl Ether as Negishi Coupling Partner: An Approach for Constructing C-C Bond under Mild Conditions |
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Aluminepin: Aluminum Analogues of Borepin and Gallepin |
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Photoinversion of Cisoid/transoid Binaphthyls |
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Expanding the tools available for direct ortho cupration – targeting lithium phosphidocuprates |
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Highly Stereoselective Synthesis of a-Alkyl-a-Hydroxycarboxylic Acid Derivatives Catalyzed by a Dinuclear Zinc Complex |
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Organic Synthesis with Zinc Reagents |
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Finding Reaction Pathways for Multicomponent Reactions: The Passerini Reaction Is a Four-Component Reaction |
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Calix[3]amide-based anion receptors: High affinity for fluoride ion and a twisted binding model |
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Helical Chirality of Azobenzenes Induced by an Intramolecular Chiral |
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Electron or Hole-Transporting Nature Selected by Side Chain-Directed π-Stacking Geometry: Liquid Crystalline Fused Metalloporphyrin Dimers |
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Planar Chirality of Twisted trans-Azobenzene Structure Induced by Chiral Transfer from Binaphthyls |
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Opening the Silole Ring: Efficient and Specific Cleavage of the endo-C(sp2)-Si Bond with AcOH/ROH System |
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Synthesis and Electronic Properties of an Azulene-fused Tribenzotetraazaporphyrin |
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TMP-cadmiate: A base for Efficient and Chemoselective Deprotonative Metallation Reactions of Aromatic Compounds |
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Reaction Mechanism for the LiCl-Mediated Directed Zinc Insertion: A Computational and Experimental Study |
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Regioselective Silylzincation of Phenylallene Derivatives |
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Lithium Cadmate-Mediated Deprotonative Metalation of Anisole: Experimental and Computational Study |
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Deprotonative Metalation of Substituted Benzenes and Heteroaromatics Using Amino/Alkyl Mixed Lithium-Zinc Combinations |
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1,4-Addition of Bis(iodozincio)methane to α,β-Unsaturated Ketones; Chemical and Theoretical/computational Studies |
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Azulenocyanine: A New Family of Phthalocyanines with Intense Near-IR Absorption |
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Synthesis, Reactions, and Electronic Properties of 16 π-electron Octaisobutyltetraphenylporphyrin (OiBTPP) |
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Cloning of a Novel O-Methyltransferase from Camellia sinensis and Synthesis of O-Methylated EGCG and Evaluation of their Bioactivity |
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Homoleptic Zincate-Promoted Room Temperature Halogen-Metal Exchange of Bromopyridines |
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Reaction Pathway of Methylenation of Carbonyl Compounds with Bis(iodozincio)methane |
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Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene) |
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Synthesis and Chiral Discrimination of Cyclic Aromatic Amides and the |
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Identification of Absolute Helical Structures of Aromatic Multi-layered Oligo(m-phenylurea)s in Solution |
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Synthesis of Well-Defined Hyperbranched Polyamides by Condensation Polymerization of AB2 Monomer Making Use of Changed Substituent Effects |
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Effect of Periodic Replacement of the Heteroatom on the Spectroscopic Properties of Indole and Benzofuran Derivatives |
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Gilman-Type versus Lipshutz-Type Reagents: Competition in Lithiocuprate Chemistry, |
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Deprotonative Metalation of Functionalized Aromatics using Mixed Lithium-Cadmium, Lithium-Indium, and Lithium-Zinc Species |
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Theoretical Study on the Halogen-Zinc Exchange Reaction Using Organozinc Ate Compounds |
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Application of the Perimeter Model to Assignment of Electronic Absorption Spectra of Gold(III) Hexaphyrins with [4n+2] and [4n] π-Electron Systems |
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Fluorescent Probe for Zn2+ with Light-Harvesting Pyrenyl Groups: Sensitization via Intramolecular Energy Transfer, |
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Design and Function of Ate Complexes, |
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A Mixed Alkyl-amido Aluminate as a Kinetically Controlled Base, |
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Generation and Suppression of 3-/4-Functionalized Benzynes Using Zinc Ate Base (TMP-Zn-ate): New Approaches to Multi-substituted Benzenes, |
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'Conformational' Solvatochromism: Spatial Discrimination of Nonpolar Solvents Using a Supramolecular Box of a π-Conjugated Zinc Bisporphyrin Rotamer |
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Development of Highly Chemoselective Bulky Zincate Complex, : Design, Structure, and Practical Applications in Small-/Macro-molecular Synthesis |
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Deprotonative Metalation of Five-membered Aromatic Heterocycles Using Mixed Lithium-Zinc Species, |
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A New Interpretation of the Reaction Pathway of Deprotonative Metalation with TMP- |
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Suppressing the Anionic Fries Rearrangement of Aryl Dialkylcarbamates; the |
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Electronic Structures of Azulene-fused Porphyrins as Seen by Magnetic Circular Dichroism and TD-DFT Calculations, |
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Solid-phase Synthesis of Phthalocyanine and Tetraazaporphyrin Triangular Prisms, |
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Deprotonative Cadmation of Functionalized Aromatics, |
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Silylmetalation of Alkenes, |
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Design and Function of Heteroleptic Zinc Ate Complexes, |
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Regio- and Chemoselective Silylmetalation of Functionalized Alkenes, |
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An Aluminum Ate Base: Its Design, Structure, Function and Reaction Mechanism, |
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Anti-[2.2](1,4)Phthalocyaninophane: Spectroscopic Evidence for Transannular Interaction in the Excited States, |
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On the Kinetic and Thermodynamic Reactivity of Lithium Di(alkyl)amidozincate Bases in Directed Ortho Metalation, |
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Reaction Pathway of Conjugate Addition of Lithium Organozincates to s-Trans Enones, |
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Direct ortho Cupration: A New Route to Regioselectively Functionalized Aromatics, |
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Origin of Chemoselectivity of TMP-Zincate Base: Differences between TMP-Zincate and Alkyllithium Reagents, |
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Ligand-Activated Lithium-Mediated Zincation of N-Phenylpyrrole, |
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Reverse Photochromic Behavior of Iron-Magnesium Complex, |
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Theoretical Studies on Ortho Oxidation of Phenols with Dioxygen Mediated by Dicopper Complex: Hints for a Catalyst with the Phenolase Activity of Tyrosinase, |
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Zinc, |
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Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building, |
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Toward a Protecting-Group-Free Halogen-Metal Exchange Reaction: Practical, Chemoselective Metalation of Functionalized Aromatic Halides Using Dianion-Type Zincate, |
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Structure and Reaction Pathway of TMP-Zincate: Amido Base or Alkyl Base?, |
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Regiocontrolled Intramolecular Cyclizations of Carboxylic Acids to Carbon-Carbon Triple Bonds Promoted by Acid or Base Catalyst, |
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Spontaneous Resolution of Aromatic Sulfonamides: Effective Screening Method and Discrimination of Absolute Structure, |
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Oligomers of β-Amino Acid Bearing Nonplanar Amides form Ordered Structures, |
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Construction of anomalously bent biphenyl structure using conformational properties of calix[4]amide, |
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The Chemistry of Dianion-type Zinc Ate Complexes, |
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Cp2TiCl2-catalyzed
Regio- and Chemoselective One-step Synthesis of γ-Substituted
Allylsilanes from Terminal Alkenes Using Dianion-type Zincate
(SiSiNOL-Zn-ate), |
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Inductive Effect-Assisted
Chain-Growth Polycondensation. Synthetic Development from para-
to meta-Substituted Aromatic Polyamides with Low Polydispersities.,
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Helical
Structures of N-Alkylated Poly(p-benzamide)s, |
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Definitive Assignments
of the Visible-Near-IR Bands of Porphyrin-Naphthalocyanine Rare-Earth
Sandwich Double and Triple Decker Compounds by Magnetic Circular
Dichroism Spectroscopy, |
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Magnetic
Circular Dichroism Study of Directly Fused Porphyrins, |
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Molecular Design
of Functional Ate Complexes, |
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Regio-
and Chemoselective Direct Generation of Functionalized Aromatic
Aluminum Compounds Using Aluminum Ate Base, |
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Development of
a Catalytic Electron Transfer System Mediated by Transition
Metal Ate Complexes, |
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Mechanism
and Ligand-transfer Selectivity of 1,2-Addition of Organozincate
Complexes to Aldehyde, |
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Chemoselective
Silylzincation of Functionalized Terminal Alkynes Using Dianion-type
Zincate (SiBNOL-Zn-ate): Regio-controlled Synthesis of Vinylsilanes,
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A
New Chemoselective Anionic Polymerization Method for Poly(N-isopropylacrylamide)
(PNIPAm) in Aqueous Media: Design and Application of Bulky Zincate
Possessing Little Basicity, |
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An
Evaluation of Amide Group Planarity in 7-Azabicyclo[2.2.1]heptane
Amides. Low Amide Bond Rotation in Solution., |
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4H-1,2-Benzoxazines
with Electron-withdrawing Substituents on the Benzene Ring.,
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Stereoselectivity of Superacid-Catalyzed Pictet-Spengler Cyclization Reactions, |
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Generation
of Functionalized Asymmetric Benzynes Using TMP-Zincates. Effects
of Ligands on Selectivity and Reactivity of Zincates., |
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Molecular Basis of Pimaran Compounds as Novel Activators of Large-Conductance |
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Mesityllithium
as a Reagent for Chemoselective Halogen-Lithium Exchange Reaction,
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Palladium Catalyzed
Arylation of Malonate Accompanying In Situ Dealkoxycarbonylation.,
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Regiocontrolled
Deprotonative-zincation of Bromopyridines Using Aminozincates.,
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Preparation and
Reactions of Pyridinyl Tellurides., |
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TMP-Zincate
as Highly Chemoselective Base for Directed Ortho Metalation.,
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New Formulas for
Organozincate Chemistry., |
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First
Observation of Zn-CN Bond in "Highly Coordinated"
Mixed Organozincates by EXAFS Spectroscopy., |
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Design, Reactivities,
and Practical Application of Dialkylzinc Hydride Ate Complexes
Generated in situ from Dialkylzinc and Metal Hydride., |
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Unique
Reactivities of Highly Coordinated Ate Complexes of Organozinc
Derivatives, |
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