野村　光城

    Mitsushiro NOMURA

基礎科学特別研究員

1975年生まれ		  

1999年3月 上智大学　理工学部化学科　卒業
（有機化学研究室　梶谷　正次　教授）
2001年3月 上智大学大学院　理工学研究科化学専攻　博士前期課程　修了
（有機化学研究室　梶谷　正次　教授）
修士論文　「イミド架橋型コバルタジチオレン錯体の反応性および電気化学的挙動」
2004年3月 上智大学大学院　理工学研究科化学専攻　博士後期課程　修了
（有機化学研究室　梶谷　正次　教授）
博士論文　"Study on the Reactions of Metalladithiolene Complexes with Azides−Reactivities of Imido-Bridged Metalladithiolene Complexes−"


2004年4月 上智大学　理工学部化学科　助手（梶谷　正次　教授）
2005年1月 CNRS-Université d' Angers(France) 博士研究員　（Dr.Marc Fourmigué）
2006年1月 CNRS-Université de Rennes 1(France) 博士研究員　（Dr.Marc Fourmigué）
2007年4月 University of Rochester (USA) 博士研究員　(Prof. Richard Eisenberg)
2008年4月 上智大学 理工学部　物質生命理工学科　特別研究員　(梶谷　正次　教授)
2009年2月 理化学研究所　加藤分子物性研究室　特別研究員　(加藤　礼三主任)
2010年4月 理化学研究所　加藤分子物性研究室　基礎科学特別研究員　(加藤　礼三主任)
2012年12月 当研究室卒業（東京化成工業株式会社へ）


　　　　・π共役系金属ジチオレン錯体を用いた分子性導体の合成開発
　　　　・有機金属錯体、非ウェルナー錯体を用いた分子性導体の合成開発


  1. M. Nomura, F. Imamura, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    Syntheses and Electrochemistry of Organometallic Cobaltadithiaazulenes
    Inorg. Chem., 51(20), 10695-10703 (2012).    New!

  2. M. Nomura, K. Harada, T. Suzuki, M. Kajitani, and T. Sugiyama
    Square-Planar Metal Dithiolene Complexes (M = Ni, Au) Exhibiting cis and trans Forms Based on Structurally Flexible o-Xylylene Backbone
    Polyhedron, 47(1), 9-15 (2012).    New!

  3. M. Nomura, T. Nakamura, Y. Kashimura, T. Sugiyama, and M. Kajitani
    Syntheses and Structural Diversity of Salicylideneaniline Derivatives with Cobaltadithiolene Backbone
    J. Mol. Struct., 1008, 77-82 (2012).    New!

  4. M. Nomura, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    Diverse Reactivities of Aromaticity-Unsaturation Coexisted Metalladithiolene Rings
    J. Organomet. Chem., 696(25), 4018-4038 (2011).

  5. M. Nomura, N. Sakamoto, H. Nakajima, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    Syntheses and Reactivities of Azido Coordinated CpCo(dithiolene) Complexes
    Polyhedron, 30(17), 2890-2895 (2011).

  6. M. Nomura, K. Terada, A. Onozawa, Y. Mitome, T. Sugiyama, and M. Kajitani
    Pd-Catalyzed Boronations and Cross-Coupling Reactions of Aromatic Cobaltadithiolene Complexes with Aryl Halides
    J. Organomet. Chem., 696(14), 2720-2727 (2011).

  7. M. Nomura, S. Iida, K. Seki, K. Kobayashi, G. Hagino, S. Horikoshi, T. Sugiyama, A. Sugimori, and M. Kajitani
    Rare Direct Imidation of Pseudo Aromatic Metallacycle by Reaction of CpCo(dithiolene) Complexes with N-Halosuccinimide
    J. Organomet. Chem., 696(9), 1723-1728 (2011).

  8. M. Nomura
    Organometallic Dithiolene Complexes of the Group 8-10 Metals: Reactivities, Structures and Electrochemical Behavior
    Dalton Trans., 40, 2112-2140 (2011).

  9. M. Nomura, M. Kanamori, N. Tateno, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    Two Near-UV and Visible Chromophores of CpCo(Dithiolene) Complexes with Pyridinium-Dicyanomethylide Group
    J. Organomet. Chem., 695(22), 2432-2440 (2010).

  10. M. Nomura, S. Kondo, S. Yamashita, E. Suzuki, Y. Toyota, G. V. Alea, G. C. Janairo, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    Sulfur-Rich CpCo(dithiolene) Complexes: Isostructural or Non-Isostructural Couples of CpCo(III) with CpNi(III) Dithiolene Complexes
    J. Organomet. Chem., 695(21), 2366-2375 (2010).

  11. M. Nomura, T. Sasao, T. Sugiyama, and M. Kajitani
    Structures and Electrochemistry of Monomeric and Dimeric CpCo(dithiolene) Complexes with Substituted Benzene-1,2-dithiolate Ligand
    Inorg. Chim. Acta, 363(14), 3647-3653 (2010).

  12. M. Nomura, H. Oguro, K. Maeshima, S. Iida, S. Horikoshi, T. Sugiyama, A. Sugimori, and M Kajitani
    Sulfur-Centered and Nitrogen-Centered Radical Substitution Reactions of Aromatic CpCo(dithiolene) Complex with 2,2’-Dibenzothiazolyl Disulfide
    J. Organomet. Chem., 695(12-13), 1613-1617 (2010).

  13. M. Nomura, T. Cauchy, and M. Fourmigue
    Radical CpNi(dithiolene) and CpNi(diselenolene) Complexes: Synthetic Routes and Molecular Properties
    Coord. Chem. Rev., 254(13-14), 1406-1418 (2010).

  14. M. Nomura, K. Terada, A. Onozawa, Y. Mitome, T. Sugiyama, and M. Kajitani
    "Pd-catalyzed dithiolene-aryl cross-coupling reaction of aromatic CpCo dithiolene complex"
    Chem. Lett., 39(3), 208-209 (2010).

  15. M. Nomura, D. Takeuchi, Y. Toyota, E. Suzuki, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    "CpCo(dithiolene) complexes of highly flexible Oxddt ligand with two different Z-shaped and U-shaped structures"
    J. Organomet. Chem., 694(26), 4261-4269 (2009).

  16. M. Nomura, C. Fujita-Takayama, T. Sugiyama, A. Sugimori, and M. Kajitani
    "Rare monomeric structure of CpRh(III) dithiolene complex: Combined ESR and electronic absorption studies on electrochemically generated Rh(II) species"
    Inorg. Chem. Commun., 12(8), 711-715 (2009).

  17. M. Nomura, E. Tsukano, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    "Organometallic dithiolene complexes of benzenedithiolate analogues with π-coordinating and π-interacting Cp* ligand"
    J. Organomet. Chem., 694(19), 3116-3124 (2009).

  18. M. Nomura, T. Fujii, and M. Kajitani
    "Platinum dithiolene complexes of π-Coordinating and π-interacting η4-cyclobutadiene ligands"
    Organometallics, 28(13), 3776-3784 (2009).

  19. M. Nomura, M. Kanamori, Y. Yamaguchi, N. Tateno, C. Fujita-Takayama, T. Sugiyama, and M. Kajitani
    "Hydrogen bonding interaction of CpCo(Dithiolene) complex with monocyclic 2-pyridonyl substituent and unexpected formation of dithiolene-fused tricyclic pyridone derivative"
    J. Organomet. Chem., 694(18), 2902-2911 (2009).

  20. M. Nomura, S. Horikoshi, and M. Kajitani
    "Metal dithiolene complexes"
    J. Jpn. Soc. Colour Mater., 82(7), 296-305 (2009).

  21. M. Fourmigué, T. Cauchy, M. Nomura
    "Experimental and Theoretical Evaluation of Magnetic Coupling in Organometallic Radicals: The Eloquent Case of Face-to-Face Cp•••Cp Interactions"
    CrystEngComm, 11(8), 1491-1501 (2009).

  22. T. Masui, M. Nomura, Y. Kobayashi, K. Terada, C. Fujita-Takayama, T. Sugiyama, M. Kajitani
    "CpCoI-mediated Diels-Alder Reaction Forming Dimeric 1,3-Dithiol-2-one Derivative with Spiro Structure and Successive Formation of Novel Cobalt Dithiolene Complex"
    Chem. Lett., 37(10), 1032-1033 (2008). .

  23. P. Grosshans, P. Adkine, H. Sidorenkova, M. Nomura, M. Fourmigué, M. Geoffroy
    "[CpNi(diselenolene)] neutral radical complexes: EPR and DFT investigations"
    J. Phys. Chem. A, 112(17), 4067-4073 (2008).

  24. M. Nomura, M. Fourmigué
    "Dinuclear Cp*Cobalt Complexes of the 1,2,4,5-Benzenetetrathiolate Bis-Chelating Ligand"
    Inorg. Chem., 47(4), 1301-1312 (2008).

  25. O. Jeannin, M. Nomura, M. Fourmigué
    "Structural Flexibility of Titanocene Diselenolene Complexes: Combined Structural and VT NMR Investigations"
    J. Organomet. Chem., 692(19), 4113-4118 (2007).

  26. T. Cauchy, E. Ruiz, O. Jeannin, M. Nomura, M. Fourmigué
    "Strong Magnetic Interactions through Weak Bonding Interactions in Organometallic Radicals: Combined Experimental and Theoretical Study"
    Chem. Eur. J., 13(31), 8858-8866 (2007).

  27. M. Nomura, M. Fourmigué
    "The Contrasted Structural and Magnetic Behaviour of Two Single-Component Paramagnetic Dithiolene Complexes"
    New J. Chem., 31(4), 528-534 (2007).

  28. M. Nomura, M. Fourmigué
    "Isostructural Diamagnetic Cobalt(III) and Paramagnetic Nickel(III) Dithiolene Complexes with an Extended Benzenedithiolate Core [CpMIII(bdtodt)] (M = Co and Ni)"
    J. Organomet. Chem., 692(12), 2491-2499 (2007).

  29. M. Nomura, M. Geoffroy, P. Adkine, M. Fourmigué
    "Neutral Radical [CpNi(Dithiolene)] Complexes with Flexible, Non Planar Seven-Membered Rings: [CpNi(S2C2S2(CH2)2X)] (X: CH2, CF2, C=CH2, S, C=O)"
    Eur. J. Inorg. Chem., (24), 5012-5021 (2006).

  30. M. Nomura, T. Cauchy, M. Geoffroy, P. Adkine, M. Fourmigué
    "[CpNi(dithiolene)] (and Diselenolene) Neutral Radical Complexes"
    Inorg. Chem., 45(20), 8194-8204 (2006).

  31. M. Nomura, S. Sakaki, Y. Hoshino, C. Fujita-Takayama, M. Kajitani
    "Formations and Electrochemical Behavior of Mononuclear and Binuclear Molybdenum Dithiolene Complexes with Nitrosyl Ligands. Evidence for the Formation of a Coordinatively Unsaturated Species [Cp*Mo(NO)(dithiolene)]"
    J. Organomet. Chem., 691(15), 3274-3284 (2006).

  32. M. Nomura, M. Kajitani
    "Formations and Structures of Cobalt Dithiolene Complexes with Nitrogen Group-Substituted Cyclopentadienyl Ligand"
    J. Organomet. Chem., 691(12), 2691-2700 (2006).

  33. M. Nomura, R. Okuyama, C. Fujita-Takayama, M. Kajitani
    "New Synthetic Methods for η5-Cyclopentadienyl Nickel(III) Dithiolene Complexes Derived from Nickelocene"
    Organometallics, 24(21), 5110-5115 (2005).

  34. M. Nomura, A. Kusui, M. Kajitani
    "Reactions of 16-Electron Iridium(III) Dithiolene Complexes with Diazoalkanes: Formation and Properties of Novel Mononuclear and Binuclear Alkylidene Adducts of Iridium Dithiolene Complexes"
    Organometallics, 24(11), 2811-2818 (2005).

  35. M. Nomura, M. Fujii, K. Fukuda, T. Sugiyama, Y. Yokoyama, M. Kajitani
    "Reactivity and Electrochemical Behavior of Ruthenium Dithiolene Complexes with Coordinatively Unsaturated Metal Centers: Cycloaddition and Dimerization Reactions"
    J. Organomet. Chem., 690(6), 1627-1637 (2005).

  36. Y. Yokoyama, S. Suzuki, H. Furihata, S. Takahi, M. Nomura, M. Kajitani
    "The Development of a Novel Synthetic Method for Cyanofluoroamides Using a Cobaltadithiolene Complex"
    Synthesis, (5), 701-705 (2004).

  37. M. Nomura, H. Hatano, T. Fujita, Y. Eguchi, R. Abe, M. Yokoyama, C. Takayama, T. Akiyama, A. Sugimori, M. Kajitani
    "Formation, Structure, and Reactivities of 1:1 Adducts between Quadricyclane and (η5-Cyclopentadienyl)(1,2-diphenyl- or -dimethoxycarbonyl-1,2-ethenedithiolato)rhodium"
    J. Organomet. Chem., 689(6), 997-1005 (2004).

  38. M. Nomura, C. Takayama, M. Kajitani
    "Electrochemical Behavior of S,S'-Bridged Adducts of Square Planar Metalladithiolene Complexes [M(S2C2Ph2)2] (M = Ni, Pd, and Pt)"
    Inorg. Chim. Acta, 357(8), 2294-2300 (2004).

  39. M. Nomura, C. Takayama, T. Sugiyama, Y. Yokoyama, M. Kajitani
    "Electrochemistry and Reactivity of Cobaltadithiolene Complexes Having Sulfilimine Structure: Effects of Phosphorus Ligands Basicities and Cone Angles on the Electrochemical Behavior and on the Imido Migration to the Cp Ring"
    Organometallics, 23(6), 1305-1312 (2004).

  40. M. Nomura, C. Takayama, M. Kajitani
    "Electrochemical Behavior of Nickeladithiolene S,S'-Dialkyl Adducts: Evidence for the Formation of Metalladithiolene Radical by Electrochemical Redox Reactions"
    Inorg. Chem., 42(20), 6441-6446 (2003).

  41. M. Nomura, A. Kawakita, H. Katsuta, C. Takayama, T. Sugiyama, Y. Yokoyama, M. Kajitani
    "Reactions of Cobaltadithiolene Complexes with Aryl Azides: Formations of Nitrogen Containing Metal Chelate Rings by Substitution Reactions via Nitrene"
    J. Organomet. Chem., 681(1-2), 180-188 (2003).

  42. M. Nomura, C. Takayama, T. Sugiyama, Y. Yokoyama, M. Kajitani
    "Imido-transfer Reactions to Carbonyl Moiety Induced by the Reactions of Imido-Bridged Cobaltadithiolene Complexes with Trivalent Phosphorus Trihalides"
    J. Organomet. Chem., 674(1-2), 63-72 (2003).

  43. M. Nomura, C. Takayama, T. Sugiyama, Y. Yokoyama, M. Kajitani
    "Novel Phosphine- and Phosphite-Induced Imido Migration to a Cyclopentadienyl Ring in an Imido-Bridged Cobaltadithiolene Complex"
    Organometallics, 22(1), 195-198 (2003).

  44. M. Nomura, T. Yagisawa, C. Takayama, T. Sugiyama, Y. Yokoyama, K. Shimizu, A. Sugimori, M. Kajitani
    "Formation and Reaction of Three-Membered Cobaltathiaziridine Ring in (η5-Cyclopentadienyl)(Substituted Imido-κN-thio-κS-ethene-2-thiolato-κS)cobalt(III). Ring Opening and Closure and Transfer of Imido Group"
    J. Organomet. Chem., 611(1-2), 376-385 (2000).



・国際学会
  1. MDF2012, Miyazaki, Janan, 1-4 December, 2012
    Mitsushiro Nomura, Takao Tsumuraya, Hengbo Cui, Majed Abdel Jawad, Tsuyoshi Miyazaki, Reizo Kato
    "Multiple Band Molecular Conductors Based on Pt(dmit)2 Complex (dmit = 1,3-dithiol-2-thione-4,5-dithiolate)"

  2. ICCC-40, Valencia, Spain, 9-13 September, 2012
    Mitsushiro Nomura, Akiko Tajima, Hengbo Cui, Majed Abdel Jawad, Takao Tsumuraya, Tsuyoshi Miyazaki, Yugo Oshima, Reizo Kato
    "Novel HOMO-LUMO Band Overlapped Molecular Conductors Based on Pt(dmit)2"

  3. ICSM 2012, Atlanta, USA, 8-13 July, 2012
    Mitsushiro Nomura, Akiko Tajima, Hengbo Cui, Majed Abdel Jawad, Takao Tsumuraya, Yugo Oshima, Tsuyoshi Miyazaki, Reizo. Kato
    "Structure and Physical Properties of Platinum-dmit Radical Anion Salts"

  4. 3rd Asian Conference on Coordination Chemistry (ACCC-3), New Delhi,India, 17-20 October, 2011
    Mitsushiro Nomura, Akiko Tajima, Hengbo Cui, Satoshi Yamashita, Yugo Oshima, Hiroshi M. Yamamoto, Reizo Kato
    "Structures and Physical Properties of Conducting M(dmit)2 Radical Anion Salts with Fluorinated Onium Cations"

  5. ISCOM 2011, Gniezno, Poland, 25-30 September, 2011
    Mitsushiro Nomura, Akiko Tajima, Hengbo Cui, Satoshi Yamashita, Yugo Oshima,Hiroshi M. Yamamoto, Reizo Kato
    "Physical Properties of Some beta-M(dmit)2 Salts with Fluorinated Ammonium"

  6. Pacifichem 2010, Honolulu, Hawaii, 15-20 December, 2010
    Mitsushiro Nomura, Akiko Tajima, Hengbo Cui, Hiroshi M. Yamamoto, Reizo Kato
    "Fluorine Mimic Effect in a New Molecular Superconductor, Fluorinated Alkylammonium Salt of Pd(dmit)2"

  7. ICSM 2010, Kyoto, Japan, 4-9 July, 2010
    Mitsushiro Nomura, Akiko Tajima, Hiroshi M. Yamamoto, Reizo Kato
    "A [Pd(dmit)2] Salt with Fluorinated Ammonium"

  8. The 21th IUCr Satellite Meeting, Osaka　Senri-Life Science Center,Japan,21-22 August,2008
    Mitsushiro Nomura,Masatsugu Kajitani,Thomas Cauchy,Marc Fourmigué
    "Isostructural but Non-Isoelectronic CpCo(III)and CpNi(III) Dithiolene Complexes"

  9. European Conference on Molecular Magnetism(ECMM),Hotel dos Templários,Tomar,Portugal,10-15 October,2006
    Mitsushiro Nomura,Thomas Cauchy,Michel Geoffroy,Prashant Adkine,Marc Fourmigué
    "CpNi(Dithiolene) and CpNi(Diselenolene) Neutral Radical Complexes:Strong NIR Absorption and Antiferromagnetism"

  10. 35th International Conference on Coordination Chemistry,The University of Heidelberg,Germany,21-26 July,2002
    Mitsushiro Nomura,Chikako Takayama,Toru Sugiyama,Yasuo Yokoyama, and Masatsugu Kajitani
    "A Novel Phosphine and Phosphite Induced Migration of Imido Group from Sulfur to Cyclopentadienyl Ligand in Imido-Bridged Cobaltadithiolene Complex"

  11. 34th International Conference on Coordination Chemistry,The University of Edinburgh,UK,9-14 July,2000
    Mitsushiro Nomura,Chikako Takayama,Toru Sugiyama,Yasuo Yokoyama,Kunio Shimizu, and Masatsugu Kajitani
    "Electrochemical Behavior of an Imido-Bridged Cobaltadithiolene Complex"



  1. 2004年3月 第84春季年会　学生講演賞
    「5配位ルテニウムジチオレン錯体の環化付加反応と電気化学的挙動」





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